Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, 2081-44-9, the author is Fernandez-Salas, Jose A. and a compound is mentioned, 2081-44-9, Tetrahydro-2H-pyran-4-ol, introducing its new discovery.
Intermolecular alkyl radical additions to enantiopure N-tert-butanesulfinyl aldimines
The sulfinyl group in (R)-N-tert-butanesulfinyl aldimines provides efficient control of the stereoselectivity in the intermolecular reactions with alkyl radicals. The methodology is applicable to aryl, heteroaryl, benzyl, and alkynyl imines, even those containing CN, CO2Me, COR, and OH groups. The best results are attained with hindered radicals (tertiary and secondary ones) without C=N bond reduction. This reaction complements the well-established organometallic additions to N-sulfinyl aldimines to obtain enantiomerically pure functionalized alpha-branched primary amines.
But sometimes, even after several years of basic chemistry education,, 2081-44-9 it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about 2081-44-9!
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics