An article , which mentions 499-40-1, molecular formula is C12H22O11.499-40-1, The compound – (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal played an important role in people’s production and life.
Complexes of copper(II) dihalide with 2,2?-dipyridylamine. X-ray diffraction structures of the [dibromo-bis(dipyam)copper(II)]-water (1:2) and di[chloro-bis(dipyam)copper(II)]diiodide-acetonitrile (1:2) complexes
The formation of complexes between copper(II) halides and 2,2?-dipyridylamine (dipyam) has been studied systematically. Only complexes with a 1:1 and 1:2 metal-to-ligand ratio are formed. Some mixed chloro-iodide and halide-PF6 compounds have also been isolated. The X-ray diffraction structures of the [Cu(dipyam)2Br2] ¡¤ 2H2O (I) and the [Cu(dipyam)2Cl]2I2 ¡¤ 2CH3CN (II) complexes are reported. I is a rare example of an octahedral coordination among the copper(II) halide complexes of dipyam. The two bromo atoms, which occupy the apical positions, are H-bonded to the water molecules of crystallization. II is a dimer, where each copper forms a cationic chloro-complex of approximately trigonal bipyramidal geometry, the dimerization being due to hydrogen bonds formed by the NH group of one of the two dipyams coordinated to each metal atom with the chlorine atom of the centrosymmetric cationic complex. The iodide anions are hydrogen-bonded to the NH groups of the dipyams not involved in the dimerization.
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Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics