The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article£¬once mentioned of 499-40-1, name: (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal
The coordination chemistry of mono(di-2-pyridylamine) copper(II) complexes with monovalent and divalent oxoanions: Crystal structure, spectroscopic and magnetic properties of dinuclear [Cu(L)(mu-H2PO4)(H 2PO4)]2 and polynuclear [Cu(L) (mu3-HPO4)]n
The crystal structures of two copper(II) complexes containing the ligand di-2-pyridylamine (dpyam) with monovalent H2PO4 – and divalent HPO42- oxoanions, [Cu(dpyam)(mu-H2PO4-O,O?)(H 2PO4)]2 (1) and [Cu(dpyam)(mu3- HPO4-O,O?,O?)]n (2), are reported and determined by X-ray crystallography. The dinuclear Cu(II) complex 1 was obtained by the reaction of dpyam with Cu(NO3)2¡¤ 3H2O and KH2PO4 in a water-ethanol (45/55) mixture. The molecules are linked into dinuclear units by two bridging didentate dihydrogenphosphate groups (endo/exo) in an equatorial-equatorial configuration giving a slightly distorted square pyramidal stereochemistry. The Cu-Cu contact distance of 5.136(2) A? is unusually large due to the exo/endo binding of the phosphate bridges. Complex 2 is a polymeric copper(II) derivative with helical [Cu(HPO4)]3 units surrounded by dpyam ligands and stabilized by intermolecular hydrogen bonds. Two nearest Cu(II) ions are bridged by a tridentate hydrogenphosphate group which is didentately coordinated to one copper(II) ion, and monodentately coordinated to another in an equatorial-equatorial configuration in an unusual bridging coordination mode. Each copper(II) ion in 2 exhibits a tetrahedrally distorted square-based geometry with the third oxygen atom (Cu-O=2.719(3) A?), from the hydrogenphosphate group weakly bound in an approximately axial position giving an extremely tetrahedrally distorted square-based pyramidal CuN 2O2O? chromophore. The magnetic susceptibility measurements (5-300 K) reveals an antiferromagnetic interaction with J values of -2.85(1) and -26.20(2) cm-1 for complexes 1 and 2, respectively. Some magneto-structural trends are discussed, along with their EPR and electronic reflectance spectra and compared with those of related complexes.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, you can also check out more blogs about499-40-1
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics