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Formation of LacNAc mimetics employing novel donor substrates for enzymatic beta1?4 galactosylation
The formation of LacNAc mimetics employing novel donor substrates for enzymatic beta1?4 galactosylation is discussed. In examining C-6 modified 4-nitrophenyl beta-D-galacto-pyranosides as donor structures the beta-galactosidase revealed a broad substrate specificity which allowed synthesis of various disaccharide components. The important role of carbohydrates in vital biological recognition processes has increasingly stimulated efforts in glycoconjugate research. Based on the findings, the primary alcohol function in galactosides does not seem to be crucial for recognition.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics