2081-44-9, Name is Tetrahydro-2H-pyran-4-ol, molecular formula is C5H10O2, belongs to Tetrahydropyrans compound, is a common compound. In a patnet, once mentioned the new application about 2081-44-9, Product Details of 2081-44-9
Electronic structure contributions towards the Anomeric effect
The anomeric effect in saccharides, manifested by an unusual stabilization of axial isomers with respect to equatorial ones at one of the carbon atoms in pyranose rings, has been proposed to originate in steric interactions with the lone pair of the pyranoid oxygen atom, or in differences in dipole moments, or in hyperconjugation. Here, we revisit this topic with computational methods, assessing the contribution of various factors towards the anomeric effect on models such as cyclohexanol, tetrahydropyran-2-ol, tetrahydropyran-4-ol, and piperidin-2-ol. Dipole moments, molecular orbitais corresponding to interaction between the lone pairs of the two oxygen, and axial-axial noncovalent interactions are thus considered and their effects estimated.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 2081-44-9. In my other articles, you can also check out more blogs about 2081-44-9
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics