In an article, published in an article, once mentioned the application of 10343-06-3, Name is 2,3,4,6-Tetra-o-acetyl-D-glucopyranose,molecular formula is C14H20O10, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 10343-06-3
Synthesis of 3,3?-neotrehalosadiamine and related 1,1?-aminodisaccharides using disarmed, armed, and superarmed building blocks
Here we report a high yielding, stereoselective synthesis of the naturally occurring 1,1?-disaccharide neotrehalosadiamine (NTD) and some related analogs. Following an eleven-step sequence, seven of which did not require chromatographic separation, NTD was generated in 60% overall yield from the inexpensive, commercially available precursor 1,2:5,6-di-O-isopropylidene- alpha-delta-glucofuranose. The key a,b-linkage of NTD was formed in a highly stereoselective manner by taking advantage of the participating effect of the acyl group at O-2 of the donor glycoside. The influence of electronic effects of disarmed, armed, and superarmed glycosyl donors and acceptors on the outcome of 1,1?-glycosidation was also observed. Antibacterial studies using NTD and its analogs show detectable but weak antistaphylococcal activity.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics