In an article, published in an article, once mentioned the application of 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal,molecular formula is C12H22O11, is a conventional compound. this article was the specific content is as follows.Computed Properties of C12H22O11
Synthesis and coordination chemistry of 2-(Di-2-pyridylamino)pyrimidine; Structural aspects of spin crossover in an FeII complex
2-(Di-2-pyridylamino)pyrimidine (L), a potentially ditopic tetradentate ligand, was synthesized from commercially available di-2-pyridylamine and 2-chloropyrimidine. Despite being capable of bridging two metal atoms with bidentate chelation of both metal centres, L prefers to chelate or bridge through the more basic pyridyl donors of the di-2-pyridylamine moiety. Mononuclear trans-[Fe(NCS)2(L)2] and [Cu(L) 2(H2O)](BF4)2¡¤H2O complexes, and a discrete [Ag2(L)4](PF6) 2 metallo-macrocycle, were isolated and structurally characterized by X-ray crystallography. A mononuclear palladium complex [PdCl 2(L)]¡¤(solvate), where solvate=1/2H2O or CH2Cl2, was also readily obtained in 71% yield. One example of the ligand acting as a bis(bidentate) bridging ligand was observed in a dinuclear [(PdCl2)2(L)]¡¤3/4H2O complex that was obtained only in very low yield (?3%) from the reaction that produced [PdCl2(L)]¡¤1/2H2O. trans-[Fe(NCS)2(L)2] undergoes a temperature-dependent high-spinlow-spin crossover at ?205K that was observed by X-ray crystallography and magnetic measurements, and attempts were made to understand the structural basis of this process. Despite efforts to isolate examples of L bridging two iron(ii) centres, only the mononuclear trans-[Fe(NCS) 2(L)2] species could be obtained.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics