713-95-1, Name is 6-Heptyltetrahydro-2H-pyran-2-one, molecular formula is C12H22O2, belongs to Tetrahydropyrans compound, is a common compound. In a patnet, author is Moskalev, Mikhail V., once mentioned the new application about 713-95-1, Recommanded Product: 713-95-1.
Alkali Metal Reduction of 1,2-Bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene (Ar-BIG-bian) to Radical-Anion
Reduction of Ar-BIG-bian (1, 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) with one molar equivalent of Li, Na or K in tetrahydrofuran (THF) affords corresponding radical-anionic salts (Ar-BIG-bian)M(THF) (M=Li, 2; Na, 3; K, 4). Compounds 2-4 were isolated in good yields and characterized by the elemental analysis, IR and ESR spectroscopy as well as the single-crystal X-Ray analysis. Bulky Ph-2(H)C groups in Ar-BIG-bian ligand prevent dimerization of complexes 2-4 and limit a number of coordinated THF molecules to one. In all three products a saturation of the alkali metal coordination sphere is achieved through an interaction with Ph rings of Ph-2(H)C substituents.
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Reference:
Tetrahydropyran – Wikipedia,
,Tetrahydropyran – an overview | ScienceDirect Topics