A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article,once mentioned of 499-40-1, Computed Properties of C12H22O11
The new complexes of formulae PPh4[Cr(dpa)(ox)2] (1), AsPh4[Cr(dpa)(ox)2] (2), Hdpa[Cr(dpa)(ox)2]·4H2O (3), Rad[Cr(dpa)(ox)2]·H2O (4) and Sr[Cr(dpa)(ox)2]2·8H2O (5) [PPh4=tetraphenylphosphonium cation; AsPh4=tetraphenylarsonium cation; dpa=2,2?-dipyridylamine; ox=oxalate dianion; Rad=2-(4-N-methylpyridinium)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1- oxyl-3-N-oxide] have been prepared and characterised by single-crystal X-ray diffraction. The structures of 1-4 consist of discrete [Cr(dpa)(ox)2]- anions, tetraphenyl- phosphonium (1), tetraphenylarsonium (2), monoprotonated Hdpa (3) and univalent radical (4) cations and uncoordinated water molecules (2-4). The chromium environment in 1-4 is distorted octahedral with Cr-O bond distances between 1.982(2)-1.946(2) A and Cr-N bonds of 2.0716(17)-2.048(3) A. The angles subtended at the chromium atom by the two oxalates are 83.6(2)-81.71(8), whereas the N-Cr-N angles are 87.76(7)-86.24(9). The [Cr(dpa)(ox)2]- unit of 1-4 is also present in 5 but it acts as a chelating ligand through its two oxalato groups towards divalent strontium cations, yielding heterobimetallic zig-zag chains that run parallel to the a axis. Each chain is formed of diamond-shaped units sharing the strontium atoms, while the two other corners are occupied by two crystallographically independent chromium atoms. The [Cr(dpa)(ox)2]- unit in 5 retains the environment observed in 1-4 and the strontium atom is coordinated to eight oxalate oxygens from four oxalate ligands. The two crystallographycally independent chromium centres within each double chain have opposite chirality. However, the adjacent double chains are related by an inversion centre resulting in achiral layers parallel to the ac plane. The magnetic properties of 1-5 have been investigated in the temperature range 1.9-290 K. A quasi Curie law behaviour is observed for 1-3 and 5 in agreement with their crystal structures, whereas a significant antiferromagnetic interaction between the chromium(III) and the radical centre occurs in the case of 4. The synthetic possibilities offered by the use of the heteroleptic species [CrL(ox)2]- (L=alpha-diimine-type ligand) as a ligand towards metal ions is analysed and discussed in the light of the available structural results.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H22O11. In my other articles, you can also check out more blogs about 499-40-1
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics