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Chemical research careers are more diverse than they might first appear, as there are many different reasons to conduct research and many possible environments. Introducing a new discovery about 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, name: (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal.
Eight novel three-coordinate boron compounds with the general formula BAr2L, in which Ar is mesityl and L is a 7-azaindolyl- or a 2,2?-dipyridylamino-functionalized aryl or thienyl ligand, have been synthesized by Suzuki coupling, Ullmann condensation methods, or simple substitution reactions (L = p-(2,2?-dipyridylamino)-phenyl, 1; p-(2,2?-dipyridylamino)biphenyl, 2; p-(7-azaindolyl)phenyl, 3; p-(7-azaindolyl) biphenyl, 4; 3,5-bis(2,2?-dipyridylamino) phenyl, 5; 3,5-bis(7-azaindolyl) phenyl, 6; p-[3,5-bis(2,2?-dipyridylamino) phenyl]phenyl, 7; 5-[p-(2, 2?-dipyridylamino)phenyl]-2-thienyl, 8). The structures of 1, 3, and 5-7 have been determined by X-ray diffraction analyses. These new boron compounds are bright blue emitters. Electroluminescent devices using compound 2 or 8 as the emitter and the electron-transport layer have been successfully fabricated. Molecular orbital calculations (Gaussian 98) have established that the blue emission of compounds 1-8 originates from charge transfer between the piorbital of the ligand L and the ppi orbital of the boron center. The ability of these boron compounds to bind to metal centers to form supramolecular assemblies was demonstrated by treatment of compound 2 with Zn(O2CCF3)2, which generated a 1:1 chelate complex {2·Zn(O2CCF3)2} (10), and also by treatment of compound 4 with AgNO3, yielding a 2:1 coordination compound {(4)2·Ag(NO3} (11). In the solid state, compounds 10 and 11 form interesting head-to-head and tail-to-tail extended structures that host solvent molecules such as benzene.
Do you like my blog? If you like, you can also browse other articles about this kind. name: (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal. Thanks for taking the time to read the blog about 499-40-1
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics