In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article，once mentioned of 499-40-1, Synthetic Route of 499-40-1
[Mn(SCN)2(L)4/2] where L = py, gamma-pic, pyCH 2OH, py-NH-py (dpa) complexes have been prepared and studied by IR and UV-Vis spectroscopy, and X-ray crystallography. Electronic structures of the complexes were calculated using DFT method, and the descriptions of frontier molecular orbitals and the relocation of the electron density of the compounds were determined. The differences in acceptor properties of the used pyridine derivatives ligands were shown in the values of ligand field parameters determined from electronic spectra of the complexes. The magnetic properties revealed paramagnetic behavior with a weak ferromagnetic interaction and the van Vleck contribution for [Mn(SCN)2(py)4] (1), ideal paramagnetism for [Mn(SCN)2(gamma-pic)4] (2) and a weak antiferromagnetic interaction and diamagnetic contribution for [Mn(SCN) 2(pyCH2OH)2] (3).
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics