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Iodine has been shown to be a general promoter for the activation of ‘armed’ glycosyl donors in glycosylation reactions. Donors that can be activated include: thio-orthoesters, glycosylsulfoxides, selenides, phosphites and imidates, and pentenyl glycosides.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics