Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps. 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article，once mentioned of 499-40-1, Product Details of 499-40-1
A silsesquioxane cage polymer functionalized with eight chloropropyl arms (1, T8-PrCl) reacted with 2,2?-dipyridiylamine (DPA) to afford a new derivative with eight pendant linear chains (2, T8-Pr-DPA). Further reaction with [Mo(eta3-C3H5)Br(CO) 2(NCMe)2] afforded another derivative containing three molybdenum units (3, T8-Pr-DPA-Mo), after substitution of the two nitrile ligands in each complex. These are the first silsesquioxane species containing DPA and the Mo(eta3-C3H5)Br(CO) 2 fragment. The three materials were characterized by 1H, 13C, 29Si, and 95Mo NMR, FTIR, XRD, and elemental analysis, and T8-PrCl (1) was also structurally characterized by single-crystal X-ray diffraction. It was identified as a low-temperature polymorph of this material. Elemental analysis indicated that all Cl atoms in the parent material T8-PrCl (1) were substituted by the deprotonated DPA group in T8-Pr-DPA (2). However, only three [Mo(eta3-C3H5)Br(CO)2(DPA)] units were detected in T8-Pr-DPA-Mo (3). A comprehensive NMR study, complemented with DFT calculations, was carried out in order to detect the effect of Mo coordination on the cage silicon and on the protons and carbons of the propyl chain, but no significant effects were observed. Both 1H and 29Si chemical shifts vary upon introducing DPA but remain the same after reaction with the Mo(II) precursor. The 95Mo NMR data reveal that the metal is not sensitive to the cage. The catalytic activity of 3 was tested as a precursor in the epoxidation of cyclooctene and styrene in the presence of TBHP. Despite the high selectivity toward the epoxides, the conversion and turnover frequencies were low, reflecting the behavior of the [Mo(eta3-C3H5)Br(CO)2(DPA)] complex.
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics