In heterogeneous catalysis, the catalyst is in a different phase from the reactants. At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. In an article, once mentioned the application of 1768-64-5, Name is 4-Chlorotetrahydropyran,molecular formula is C5H9ClO, is a conventional compound. this article was the specific content is as follows.Formula: C5H9ClO
In the context of [3+6+3+6] macrocyclization reactions, precise kinetics of alpha-diazo-beta-ketoester decomposition were measured by in situ infrared (IR) monitoring. Dirhodium complexes of Ikegami-Hashimoto type – and perchlorinated phthalimido derivatives in particular – performed better than classical achiral complexes. Clear correlations were found between speciation among dirhodium species and catalytic activity. With these results, novel cyclohexyl-derived catalysts were developed, affording good yields of macrocycles (up to 78%), at low catalyst loadings (from 0.01 mol% to 0.001 mola?%) and on a large scale (from 1 g to 20 g).
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics