Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice can avoid electrode passivation, which strongly inhibit the efficient activation of substrates. 14215-68-0, Name is N-((2S,3R,4R,5R,6R)-2,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)acetamide, molecular formula is C8H15NO6. In a Article，once mentioned of 14215-68-0, SDS of cas: 14215-68-0
Glycosidases are valuable catalysts for the synthesis of a wide array of di- and oligosaccharides. Herein we report on the use of beta-1-N-acetamido-2- acetamido-2-deoxy-d-glucopyranose, the simple model of the N-glycoprotein linkage region, as a novel acceptor for disaccharide synthesis catalyzed by beta-N-acetylhexosaminidases from Aspergillus oryzae and mung beans (Vigna radiata) under transglycosylation as well as reversed hydrolysis. The exclusive formation of the disaccharide model, beta-d-GlcNAc-(1?4)-d- GlcNAcbetaNHAc, by transglycosylation and the corresponding (1?6) analog under reversed hydrolysis both in reasonable yields demonstrates the versatility of beta-N-acetylhexosaminidase from Aspergillus oryzae. The efficacy of the enzyme from Vigna radiata for synthesis has been demonstrated for the first time. This is also the first report on the use of derivatized sugars as co-reactants in glycosidase catalyzed reversed hydrolysis mode of synthesis. The excellent (1?6) selectivity of mung beans beta-N-acetylhexosaminidase under transglycosylation and that from Aspergillus oryzae under reversed hydrolysis would prove to be very useful.
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics