Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice can avoid electrode passivation, which strongly inhibit the efficient activation of substrates. 74808-09-6, Name is (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate, molecular formula is C36H36Cl3NO6. In a Article,once mentioned of 74808-09-6, SDS of cas: 74808-09-6
Tetra-O-benzylglucose 1 and trichloroacetonitrile afford in a base catalyzed, fast, and reversible reaction the beta-O-glycosyl imidate 3-beta, which is transformed slowly into the alpha-isomer 3-alpha.Both results, the reactivity differences of 2alpha,beta and the stability differences of 3-alpha/beta are due to lone pair repulsions implicated in the anomeric effect.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics