The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.409346-73-2, Name is 6-Fluorochromane-2-carbaldehyde, molecular formula is C10H9FO2. In a Article£¬once mentioned of 409346-73-2, Recommanded Product: 409346-73-2
Infrared and 23Na double rotation nuclear magnetic resonance studies for intrazeolite anchoring of rhodium carbonyl clusters
The synthesis of intra-Na56Y zeolite anchoring of [Rh6(CO)12(I?3-CO)4] involves the deposition of [Rh(CO)2Cl]2 vapor into the Na56Y cavities followed by reductive carbonylation under a mixed CO and H2O atmosphere. The physicochemical characterization was based on a multianalytical approach, including Fourier transform infrared and 23Na double rotation (DOR) nuclear magnetic resonance (NMR) spectroscopies and CO gas chemisorption. The decarbonylated species of the intrazeolitic [Rh6(CO)12(I?3-CO)4] is proposed to contain a Rh4 cluster, which reacts with CO at low temperature, generating [Rh4(CO)9(I?2-CO)3] clusters, and with CO and H2O at high temperature to form [Rh6(CO)12(I?3-CO)4] clusters. 23Na DOR NMR signal shifts of the site II Na+ cations in the Na56Y supercages and infrared band shifts of bridging CO ligands in the [Rh6(CO)12(I?3-CO)4]- Na56Y provide complementary evidence for the anchoring of [Rh6(CO)12(I?3-CO)4] inside the supercages. These patterns suggest that a strong interaction occurs between the oxygen end of face-bridging CO ligands and the site II Na+ supercage cations.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 409346-73-2, you can also check out more blogs about409346-73-2
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics