In an article, published in an article, once mentioned the application of 14215-68-0, Name is N-((2S,3R,4R,5R,6R)-2,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)acetamide,molecular formula is C8H15NO6, is a conventional compound. this article was the specific content is as follows.category: Tetrahydropyrans
Kinetic Control of Regioselectivity in Glycosidase-catalysed Disaccharide Synthesis: Preparation of 2-Acetamido-4-O-(2-acetamido-2-deoxy-beta-D-glucopyranosyl)-2-deoxy-D-glucopyranose (N,N’-diacetylchitobiose) and 2-Acetamido-6-O-(2-acetamido-2-deoxy-beta-D-glucopyranosyl)-2-deoxy-D-gluco…
During transfer of the N-acetyl-beta-D-glucosaminyl (2-acetamido-2-deoxy-beta-D-glucopyranosyl)residue from p-nitrophenyl N-acetyl-beta-D-glucosaminide (p-nitrophenyl N-2-acetamido-2-deoxy-beta-D-glucopyranoside) on to N-acetyl-D-glucosamine (2-acetamido-2-deoxy-D-glucopyranose) catalysed by the N-acetylhexosaminidase from Aspergillus oryzae, the major isomer formed was found to depend on the time course of the reaction, 1 -> 4 transfer predominating while the p-nitrophenyl glycoside was available as donor, but 1 -> 6 transfer when the initially-formed 1 -> 4 product took over as donor, results that could be interpreted in terms of a constant regioselectivity modulated by selective hydrolysis of the products.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics