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The recently isolated natural product harounoside, namely 5,10-dihydroxy-2H-naphtho[2,3-c]pyran-beta-D-bisglucopyranoside, was conveniently synthesized for the first time from pentalongin in 84% yield over three steps. Georg Thieme Verlag Stuttgart.
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics