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Characteristic aromas are usually key labels for food products. In this study, the volatile profiles and marker substances of coconut jam during concentration were characterized via sensory evaluation combined with headspace solid phase microextraction-gas chromatography-tandem mass spectrometry (HSPME/GC-MS). A total of 33 aroma compounds were detected by HSPME/GC-MS. Principal component analysis revealed the concentration process of coconut jam can be divided into three stages. In the first stage, esters and alcohols were the two main contributors to the aroma of the coconut jam. Next, a caramel smell was gradually formed during the second stage, which was mainly derived from aldehydes, ketones and alcohols. The concentration of aldehydes increased gradually at this stage, which may be the result of a combination of the Maillard reaction and the caramelization reaction. In the final sterilization stage, the ?odor intensity? of caramel reached the maximum level and a variety of aroma compounds were produced, thereby forming a unique flavor for the coconut jam. Finally, furfural fit a logistic model with a regression coefficient (r2) of 0.97034. Therefore, furfural can be used as a marker substance for monitoring the concentration of coconut jam.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 3301-94-8, Name is 6-Butyltetrahydro-2H-pyran-2-one, SDS of cas: 3301-94-8.

The present invention relates to an improved fragrance controlled release system that can be incorporated into anhydrous consumer and cosmetic products such as powder laundry detergents, underarm deodorant or antiperspirant sticks, soap bars, body deodorant powders, foot spray, hygiene sprays, feminine napkin sprays, undergarment sprays, and the like that provides a high intensity odor signal such as a high impact fragrance burst in response to moisture. A selected fragrance is encapsulated in a water-sensitive matrix material. The high impact fragrance burst in response to moisture is achieved by formulating the fragrance or fragrance ingredients that are encapsulated to provide improved fragrance release in response to moisture. The encapsulated fragrance is formulated by combining fragrance ingredients such that their interaction with water results in increasing their relative content in the headspace of the system proximate environment after the system has been exposed to moisture. Examples of suitable fragrance ingredients have ClogP<=4.0 and boiling point<=300 degrees C. The present invention also can provide multiple fragrance bursts in response to moisture. Multiple fragrance bursts can be achieved by formulating the moisture sensitive matrix material with materials having different dissolution rates. The invention further relates to anhydrous consumer and cosmetic product compositions comprising the improved fragrance controlled release system of the present invention. Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 3301-94-8. In my other articles, you can also check out more blogs about 3301-94-8

Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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A reliable Fisher discriminant model was established which was able to analyze the aroma component in milk, dairy products, flavors and fragrance, and applied on its variety identification. Foodomics was applied on screening of flavor components in 1093 dairy products and flavor samples in this study. Stepwise discrimination was used to screen the components of the dairy products and flavor samples that had a significant effect on the classification results, and discriminant function analysis. Then nine principal components were used for established the Fisher discriminant model. The three-dimensional coordinate distance of the sample was calculated and as the gist. The result showed that samples and flavors were distributed in eight different sites. The separation and clustering effects are better. The objective of the present study was to effectively determine whether or not flavors were added to dairy products.

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Tetrahydropyran – Wikipedia,
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Asymmetrically substituted 6I-VII-O-t-butyldimethylsilyl(TBDMS)-3I-VII-O-ethyl-2I-VII-O-methyl-beta-cyclodextrin (MeEt-CD) and 6I-VII-O-TBDMS-2I-VII-O-ethyl-3I-VII-O-methyl-beta-cyclodextrin (EtMe-CD) were synthesised to evaluate the role of the substitution pattern in positions 2 and 3 on the enantioselectivity, in particular in view of their application to routine analysis in fast enantioselective gas chromatography (Es-GC). The chromatographic properties and enantioselectivities of the new derivatives were tested by separating the enantiomers of a series of medium-to-high volatility racemates in the flavour and fragrance field, and compared to those of the corresponding symmetrically substituted 6I-VII-O-TBDMS-2I-VII,3I-VII-O-methyl-beta-CD (MeMe-CD) and 6I-VII-O-TBDMS-2I-VII,3I-VII-O-ethyl-beta-CD (EtEt-CD), and were then applied to analysis of real-world essential oil (e.o.) samples. A new synthetic process including the sonochemical approach to obtain synthetic reproducibility and significant yields of the per-substituted derivatives with acceptable reaction times was developed. The results show that asymmetrically substituted methyl/ethyl CDs compared to the methyl or ethyl symmetrical derivatives in general provide better enantioselectivity in terms of both enantiomer resolution and number of separated chiral compounds, and show how the substitution pattern in positions 2 and 3 of the CD ring can influence the separation. Moreover, these new CD derivatives with better enantioselectivity are also shown to be very useful in routine analysis for the exhaustive control of samples containing several chiral characterizing markers in a single run.

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Tetrahydropyran – Wikipedia,
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Mesquite (Prosopis spp.) are woody leguminous plants that belong to the family Leguminosae and grow in arid and semiarid regions of America, Africa and Asia. Prosopis spp. produce indehiscent fruit (pods) that can be milled to yield flour that is sold commercially and is used in pastries and baked goods. The major volatile constituent of mesquite flour was identified as 5,6-dihydro-6-propyl-2H-pyran-2-one on the basis of its Kovats index and mass spectrum. Using delta-nonalactone as an internal standard its concentration was determined to be 59.75 ± 7.07 mg/kg (n = 3).

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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Optical resolutions of 5-alkyl-delta-valerolactones were carried out by derivatization to the diastereomeric amides, in which (R)-(+)-1-(1-naphthyl)ethylamine or (S)-(-)-1-phenylethylamine were used as resolving agents. Optically active 5-fluoroalkanols, useful intermediates for fluorinated ferroelectric liquid crystals, were derived from the resolved lactones in four steps without racemization.

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Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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A systematic approach for the characterisation of the most important aroma-active compounds in a commercial native cold-pressed rapeseed oil on the basis of the Molecular Sensory Science Concept, consisting of aroma extract dilution analysis (AEDA), identification experiments by gas chromatography?olfactometry and gas chromatography?mass spectrometry, stable isotope dilution analysis (SIDA), calculation of odour activity values (OAVs), and recombination experiments, was performed. Forty-nine aroma-active compounds, isolated by thin layer distillation, were identified with a flavour dilution factor ?8 during AEDA and headspace AEDA, 23 thereof reported in native cold-pressed rapeseed oil for the first time. Twenty-three odorants were quantitated via SIDA revealing for 11 compounds concentrations above their respective odour thresholds. Thereby, 2-isopropyl-3-methoxypyrazine, dimethyl trisulphide, dimethyl sulphide, butanoic acid, and octanal showed the highest OAVs (ratio of concentration divided by respective odour threshold). For data validation, a reconstitution model was prepared by mixing the odorants in their natural occurring concentrations in an odourless oily matrix showing an aroma profile very similar to the profile of the original rapeseed oil, confirming that all key aroma compounds were identified and quantitated successfully.

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Tetrahydropyran – Wikipedia,
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Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Safety of 6-Butyltetrahydro-2H-pyran-2-one, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3301-94-8, in my other articles.

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 3301-94-8, Name is 6-Butyltetrahydro-2H-pyran-2-one, molecular formula is C9H16O2. In a Article,once mentioned of 3301-94-8, Safety of 6-Butyltetrahydro-2H-pyran-2-one

A high-yielding stereoselective method for forming spiroketals from simple ketoallylic diols is reported. Employing catalytic [PdCl2(MeCN) 2] in THF at 0 C, these dehydrative cyclization reactions require only mild conditions to produce vinyl-substituted spiroketals in high yields after brief reaction times with water as the only byproduct. Using this method, the stereochemical information embedded at the nucleophile is transmitted “down-the-chain” and efficiently sets the stereochemistry at both the anomeric carbon atom and the newly formed allylic stereocenter. Down-the-chain: Rapid, high-yielding dehydrative spiroketalization of ketoallylic diols is achieved by efficient catalysis with [PdCl 2(MeCN)2]. The reactions are highly selective for most substrates, with the chiral information of a single stereocenter being communicated, and cyclization occurring, in a “down-the-chain” fashion. Further stereochemical control can be gained by the incorporation of a chiral allylic alcohol (see scheme). Copyright

Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Safety of 6-Butyltetrahydro-2H-pyran-2-one, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3301-94-8, in my other articles.

Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3301-94-8, Name is 6-Butyltetrahydro-2H-pyran-2-one, molecular formula is C9H16O2. In a Review,once mentioned of 3301-94-8, Product Details of 3301-94-8

Fungal volatiles-a survey from edible mushrooms to moulds

Covering: up to January 2017 This review gives a comprehensive overview of the production of fungal volatiles, including the history of the discovery of the first compounds and their distribution in the various investigated strains, species and genera, as unravelled by modern analytical methods. Biosynthetic aspects and the accumulated knowledge about the bioactivity and biological functions of fungal volatiles are also covered. A total number of 325 compounds is presented in this review, with 247 cited references.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

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3301-94-8, Name is 6-Butyltetrahydro-2H-pyran-2-one, molecular formula is C9H16O2, belongs to tetrahydropyrans compound, is a common compound. In a patnet, once mentioned the new application about 3301-94-8, HPLC of Formula: C9H16O2

Catalytic Asymmetric Synthesis of Cyclohexanes by Hydrogen Borrowing Annulations

Hydrogen borrowing catalysis serves as a powerful alternative to enolate alkylation, enabling the direct coupling of ketones with unactivated alcohols. However, to date, methods that enable control over the absolute stereochemical outcome of such a process have remained elusive. Here we report a catalytic asymmetric method for the synthesis of enantioenriched cyclohexanes from 1,5-diols via hydrogen borrowing catalysis. This reaction is mediated by the addition of a chiral iridium(I) complex, which is able to impart high levels of enantioselectivity upon the process. A series of enantioenriched cyclohexanes have been prepared and the mode of enantioinduction has been probed by a combination of experimental and DFT studies.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics